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Journal Articles

Effects of neutron irradiation on some superplastic characteristics of tetragonal zirconia polycrystals containing 3 mol% yttria

Shibata, Taiju; Ishihara, Masahiro; Motohashi, Yoshinobu*; Ito, Tsutomu*; Baba, Shinichi; Kikuchi, Makoto*

Materials Transactions, 45(8), p.2580 - 2583, 2004/08

 Times Cited Count:3 Percentile:26.88(Materials Science, Multidisciplinary)

Fast neutrons (energy $$>$$ 1.6$$times$$10$$^{23}$$ J) were irradiated to tetragonal zirconia polycrystals containing 3 mol% yttria (3Y-TZP) at the fluence levels of 2.5$$times$$10$$^{24}$$ (Light irradiation) and 4.3$$times$$10$$^{24}$$ (Heavy irradiation) m$$^{-2}$$. The irradiation caused no significant swelling in the 3Y-TZP specimens. After the neutron irradiation, superplastic characteristics were examined by tensile tests at a temperature range from 1623 to 1773 K with initial strain rates ranging from 5.0$$times$$10$$^{-4}$$ to 1.67$$times$$10$$^{-2}$$s$$^{-1}$$. It was found that the elongation to fracture of the irradiated specimens was quite small in comparison with the unirradiated ones. The apparent activation energy for the superplastic flow of the irradiated 3Y-TZP was fairly high, i.e., 781 and 693 kJ・mol$$^{-1}$$ for Light and Heavy irradiations, respectively. Atomic displacement damages and defects in the 3Y-TZP caused by the irradiation were thought to be main causes of these property changes.

Journal Articles

Irradiation behavior of rock-like oxide fuels

Yamashita, Toshiyuki; Kuramoto, Kenichi; Shirasu, Noriko; Nakano, Yoshihiro; Akie, Hiroshi; Nagashima, Hisao; Kimura, Yasuhiko; Omichi, Toshihiko*

Journal of Nuclear Materials, 320(1-2), p.126 - 132, 2003/07

 Times Cited Count:10 Percentile:56.43(Materials Science, Multidisciplinary)

Two irradiation tests on the rock-like oxide (ROX) fuels, small disk-shape fuel targets and pellet-type fuels, were performed in order to clarify in-pile irradiation stabilities. Swelling, fractional fission gas release (FGR) and phase change were examined by puncture test, profilometry and ceramography. YSZ single-phase fuel showed an excellent irradiation behavior, ie. low fission gas release (less than 3%), negligible swelling and no appreciable restructuring. The particle dispersed fuels showed lower swelling and higher fission gas release than those of mechanically blended fuels. Spinel decomposition and subsequence restructuring in the spinel matrix fuels was observed for the first time in the present investigation. It would be possible to reduce the FGR of the spinel matrix fuels, if the maximum fuels temperature is limited below 1700 K where neither spinel decomposition nor restructuring was observed. Damaged area of spinel matrix due to fission fragment irradiation seemed to be confined to thin layers around the surface of YSZ particles.

Journal Articles

Rock-like oxide fuels and their burning in LWRs

Yamashita, Toshiyuki; Kuramoto, Kenichi; Akie, Hiroshi; Nakano, Yoshihiro; Shirasu, Noriko; Nakamura, Takehiko; Kusagaya, Kazuyuki*; Omichi, Toshihiko*

Journal of Nuclear Science and Technology, 39(8), p.865 - 871, 2002/08

 Times Cited Count:25 Percentile:81.52(Nuclear Science & Technology)

Research on the plutonium rock-like oxide (ROX) fuels and their once-through burning in light water reactors has been performed to establish an option for utilizing and disposing effectively the excess plutonium. The ROX fuel is a sort of the inert matrix fuels and consists of mineral-like compounds such as yttria stabilized zirconia, spinel and corundum. A particle-dispersed fuel was devised to reduce damage by heavy fission fragments. Some preliminary results on swelling, fractional gas release and microstructure change for five ROX fuels were obtained from the irradiation test and successive post-irradiation examinations. Inherent disadvantages of the Pu-ROX fuel cores could be improved by adding 238U or 232Th as resonant materials, and all improved cores showed a nearly the same characteristics as the conventional UO2 core during transient conditions. The threshold enthalpy of the ROX fuel rod failure was found to be comparable to the fresh UO2 rod by pulse-irradiation tests simulating reactivity initiated accident conditions.

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